Chelating bis(phosphinidenes) with cyclic alkyl(amino)carbene backbones: synthesis and coordination chemistry

This project focuses on developing new types of catalysts by designing and testing innovative molecules (ligands) that can better interact with metals and tune their properties. Catalysts are chemical species that help speed up chemical reactions, making them more efficient, selective, and sustainable. They are essential in many industries, from pharmaceuticals and petrochemicals to energy production, conversion, and storage. The proposed work will explore a promising new class of ligands called cyclic alkyl(amino)carbene-stabilized phosphinidenes, which build on the strengths of existing phosphinidene ligand systems to create ligands imparting improved stability and reactivity to the metal centers they bind to. This collaborative work will bring together the combined expertise of the two participating research groups in stable carbene and phosphorus chemistry, respectively.
By fine-tuning the structure of the phosphinidene ligands, the goal is to create metal complexes that can perform challenging chemical transformations more efficiently. This could lead to breakthroughs in green chemistry, helping reduce waste and energy consumption in industrial processes. It also provides valuable training for the training of highly qualified personnel in cutting-edge chemical techniques, fostering international collaboration in the field of advanced materials and catalysis.

Faculty Supervisor:

Roland Roesler

Student:

Partner:

Universität Regensburg

Discipline:

Physics

Sector:

Advanced Manufacturing

University:

University of Calgary

Program: