Bipolar Membranes for Electrochemical Technologies

The electrochemical splitting of water into hydrogen and oxygen gas is a technology of growing importance in the clean energy sector. Emerging technologies are employing membranes to provide physical separation of the cathode and anode compartments, thereby separating the product gases, while allowing ions to flow between the compartments to maintain the electrochemical reactions taking […]

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Stable synthetic equivalents of the monophosphorus anion (P-): a clean substitute for PCl3

Phosphorus is vital not only for food production but also for other agricultural commodities such as ethanol, biofuels, and any biorenewable chemicals. The annual worldwide production of elemental phosphorus reaches 850,000 tons, from which 18% is transformed by addition of chlorine gas into 700,000 tons/year of PCl3, the industrial precursor to most phosphorus derivatives. Significant […]

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Control of Silicon Nanocrystal Optical Response through Fueled Dissipative Self-Assembly

This project aims to prepare a self-assembling and disassembling material from silicon and gold nanoparticles. The lifetime of this material is determined by the network of chemical reactions that control the assembly and disassembly of its constituents. The relative rates of these reactions, in turn, depend on the concentration of a chemical fuel. Silicon nanoparticles, […]

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Dynamic ion speciation during hydrolysis of aryltrifluoroborates

The Suzuki-Miyaura (SM) coupling reaction is a widely studied reaction between organoboron compounds and organic halides. Over the last 30 years the reaction has been improved as new discoveries are made in relation to the reactant species. Its applications extend to pharmaceutical and natural product synthesis due to its versatility. Unfortunately, several of the mechanisms […]

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Ink-Jet Printing of Flexible Polymer Thermoelectric Devices

My doctoral project targets new solutions to recycle waste heat by turning it into electrical power. In particular, clean electrical power can be generated in a semiconductor when a temperature difference does exist between the hot and the cold side of said material. Our group at INRS-EMT has started a unique research line in Canada […]

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Pion Experiments at Jefferson Lab and Feasibility Studies for EIC

My research project will involve completing vital preparation work for two upcoming high impact experiments at a world leading research facility. I will take a lead role in preparing analysis software and equipment for these upcoming experiments at Jefferson Lab which will run towards the end of my project. I will ensure these experiments run […]

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Spectroscopie d’absorption transitoire dans la fenêtre de l’eau

La technologie laser permet aujourd’hui de générer des flashs de lumière (impulsions laser) ultra-brefs offrant une résolution temporelle attoseconde (1 attoseconde = 0.000 000 000 000 000 001 s). De telles impulsions offrent l’opportunité de suivre les mouvements ultra-rapides des noyaux atomique et des électrons dans les molécules, en temps réel. C’est ce que promet […]

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Development of functionalized iodine(III) species as organocatalysts

The iodine atom normally forms one bond with another atom. However, it can be forced to form multiple bonds, making it hypervalent. This draws away electron from the iodine, making it partially positively charged. It will thus attract and interact with negatively charged molecules or parts of molecules. This concept is Lewis acidity and can […]

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Total Synthesis of (?)-Acaranoic acid

Lichens are a symbiosis of fungi and algae or cyanobacteria. Lichen substances have been reported to show a wide array of biological activities including antiviral, antioxidant, antitumor action. This project aims to establish a reliable way to prepare (?)-acaranoic acid, a lichen substance isolated in 1895, from commercially available chemicals. The proposed synthesis of this […]

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Production d’un extrait riche en antioxydants à partir de la complémentarité et de la synergie des petits fruits par cryoconcentration et évaluation du potentiel antioxydant

L’objectif principal de ce projet est d’évaluer l’effet de la cryoconcentration pour la production d’un extrait riche en molécules antioxydantes à partir des petits fruits de la région du Lac-St-Jean. Ces études auront permis d’ouvrir la voie à des projets industriels en vue de valoriser les petits fruits produits de la région. Une analyse de […]

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Synthesis of Nanostructured Mesoporous Nickel Materials for Energy Storage Applications

With the advent of fuel cell technology, people began to believe implementation of a zero-emission energy system through the construction of a hydrogen-based energy infrastructure. The conventional system for hydrogen production is water electrolysis; however, the production cost is far too expensive for widespread adoption due to the usage of noble metals required as electrocatalysts. […]

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